Cope重排反应

反应属于[3,3]-σ单电子迁移重排,反应过程协同进行,反应可逆。机理同克莱森重排。

反应实例

参考文献

References

1. Cope, A. C.; Hardy, E. M. J. Am. Chem. Soc. 1940, 62, 441􀀐-444.

2. Frey, H. M.; Walsh, R. Chem. Rev. 1969, 69, 103-􀀐124. (Review).

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5. Hill, R. K. In Comprehensive Organic Synthesis Trost, B. M.; Fleming, I., Eds.;

Pergamon, 1991, Vol. 5, 785􀀐-826. (Review).

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8. Miyashi, T.; Ikeda, H.; Takahashi, Y. Acc. Chem. Res. 1999, 32, 815-􀀐824. (Review).

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11. Clive, D. L. J.; Ou, L. Tetrahedron Lett. 2002, 43, 4559–4563.

12. Malachowski, W. P.; Paul, T.; Phounsavath, S. J. Org. Chem. 2007, 72, 6792–6796.

13. Mullins, R. J.; McCracken, K. W. Cope and Related Rearrangements. In Name Reactions for Homologations-Part II; Li, J. J., Ed.; Wiley: Hoboken, NJ, 2009, pp 88􀀐135.

(Review).

14. Ren, H.; Wulff, W. D. Org. Lett. 2013, 15, 242–245.

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编译自:Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Cope rearrangement,page 161-162.

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