清华大学朱永法课题组--石墨烯层封装 α-MnO2 纳米纤维调整表面电子结构用于有效分解臭氧

开发用于臭氧分解的锰基材料时，遇到的主要挑战有稳定性差和水失活效应等。为了解决这些问题，这里开发了一种分级结构，即石墨烯封装的α-二氧化锰纳米纤维。优化后的催化剂在相对湿度为20%的条件下，臭氧转化效率稳定在80%以上，100小时内稳定性良好。即使相对湿度增加到50%，臭氧转化率也达到70%，远远超过纯α-二氧化锰纳米纤维的性能。这里，表面的石墨碳通过从内部不饱和锰原子中捕获电子而被活化。优异的稳定性源于适度的局部功函数，它优化了臭氧分子吸附和中间氧物种解吸时的反应势垒。疏水的石墨烯壳阻碍了水蒸气的化学吸附，从而增强了其耐水性。该工作为催化剂设计提供了重要的见解，并将促进锰基催化剂在臭氧分解中的实际应用。

Figure 1. 三维分级MnO2@GR的合成路线和模型示意图。该三位分级结构是通过硫酸锰的络合、高锰酸钾的氧化、MnO2在水热条件下的晶体生长和1D核壳纳米纤维的自组装过程合成的。

Figure 2. 三维分级的MnO2@GR的形貌。.包括SEM图，TEM图，MnO2@GR纳米纤维示意图，HAADF-STEM图和相应的EDX线性扫描，以及元素分布。

Figure 3．三维分级的MnO2@GR的结构分析。包括XRD图, Raman谱和XPS光谱，以及在0.1M Bu4NPF6电解质中的CV曲线。

Figure 4．三维分级的MnO2@GR的高效臭氧转化。a.不同样品的臭氧转化率比较。b .α- MnO2和7.50% MnO2@GR在50%相对湿度下的臭氧转化及其再生性能。c.在交替相对湿度下，7.50% MnO2@GR的臭氧转化。在50%相对湿度下负载催化剂的臭氧转化。插图:不锈钢网上涂有7.50% MnO2的照片。实验条件:0.1 g催化剂。该研究工作由清华大学朱永法课题组于2021年发表在NATURE COMMUNICATIONS期刊上。原文：Encapsulate α-MnO2nanofiber within graphene layer to tune surface electronic structure for efficient ozone decomposition。朱永法, 理学博士，教授，博士生导师1964年11月23日出生于中国, 江苏省江阴市。国家自然科学基金委杰出青年基金获得者以及教育部跨世纪优秀人才资助计划获得者。联系方法：北京100084 清华大学化学系朱永法教授电话[phone]; 传真[phone];Email：[e-mail]网页：http://166.111.28.118/myweb1981年考入南京大学，化学系。专业为物理化学，研究方向为合成氨中温变换催化剂的吸附性能。1985年从南京大学毕业，获得理学学士学位，并于同年考入北京大学，化学系攻读硕士学位。就读于桂琳琳教授和唐有祺教授，专业为物理化学，研究方向为加氢脱氮催化剂的固体表面化学。1988年研究生毕业，获得硕士学位。同年进入清华大学，化学系工作并攻读博士学位。就读于曹立礼和宋心琦教授。研究方向为固体薄膜材料的表面与界面扩散反应的研究，于1995年获得理学博士学位。从1995年10月到1997年3月，获得日本政府奖学金，在爱媛大学化学系从事博士后研究工作。就读于河野博之 (Hiroyuki Kawano)教授，主要从事固体表面卤化物的离子TPD研究。1997年3月回国后，在清华大学化学系继续从事光催化、环境催化、表面化学以及环境化学研究。《化学学报》顾问编委，“Research on Chemical Intermediates”和《物理化学学报》编委，中国环境科学学会大气分会理事，中国微束分析标准化技术委员会委员,国家计量认证高校组评审组长，ISO/TC201表面分析国际标准委员会委员,中国机械工程学会理化检验分会委员；全国环境化学计量技术委员会委员。福建省光催化重点实验室学术委员，环境污染控制与同位素应用技术广州市重点培育实验室学术委员会委员。（1） 光催化材料及其在环境净化和CO2资源化应用研究通过探索纳米结构复合氧化物光催化新材料提高光催化活性以及拓展可见光的响应范围。通过表面杂化作用，提高光催化剂的活性以及耐光腐蚀性能，同时产生可见光活性。探索表面缺陷对光催化活性提高以及产生可见光活性的内在规律。利用光催化材料对室内空气中有机物的污染和微生物污染进行净化研究。探索光催化材料在光解水制氢以及CO2光还原资源化方面的规律和机制。（2） 吸附-催化燃烧工业废气的净化研究探索非贵金属催化燃烧催化剂，通过纳米结构的控制合成，提高其低温活性以及稳定性。并利用吸附作用和催化燃烧的联用技术，解决工业废气的净化难题。（3） 室内空气的净化研究利用高活性光催化材料，通过在各种基材上形成多孔膜，提高光催化的净化性能，开展了室内空气净化的研究。探索多孔和单层g-C3N4的可控合成，通过与半导体光催化剂的杂化，探索提高可见光活性的新途径，并应用于室内自然光下的空气净化研究。1、“光催化污染控制过程中提高能量效率的方法和原理”获国家自然科学奖二等奖，2011，排名第2；2、“光催化污染控制过程中提高能量效率的方法和原理”获教育部自然科学奖一等奖,2010，排名第23、“TiO2介孔薄膜光催化剂及其环境净化用”获教育部自然科学奖二等奖,2007，排名第14、“应用纳米技术有效降低卷烟烟气中有害物质含量的研究”获中国烟草总公司科技进步奖二等奖,2010，排名第2；5、“纳米异质薄膜的界面化学状态研究”获教育部科学技术进步奖（基础类）二等奖,1999，排名第26、“加氢精制催化剂载体效应的研究”获国家教委科技进步奖甲类三等奖,1994，排名第4承担了国家973项目、863项目、国家自然科学基金杰出青年基金、仪器专项、重点和面上等科研项目。同时还与国内外的企业合作开展应用方面的研究。如P&G宝洁公司、GE公司、西门子公司、三菱重工等。已经发表SCI收录论文230余篇，其中ESI收录的Top-paper5篇，Hot-paper 1篇。论文总引用达到5000余次;发表论文的H因子为39。申请国家发明专利17相，获得授权12项。出版专著两部：《纳米材料的分析表征和测试》和《材料分析化学》。2005年以来发表论文题目、杂志、年月分类出版中Rui Shia, b, Tongguang Xub, Yongfa Zhua,*, Jun Zhoub, *, Mechanism of High Photoactivity of Oxychloride CaBiO2Cl and Role of Surface Hydroxyl on the Photocatalytic Performances,CrystEngComm, 2012Xu, Jing; Wang, Li,Zhu Yongfa*, Decontamination of bisphenol A from aqueous solution by graphene adsorption"，Langmuir ,2012Bin Lu, Xinguo Ma, Chengsi Pan, Yongfa Zhu*,Photocatalytic and Photoelectrochemical Properties of In-situ Carbon Hybridized BiPO4 films，Applied Catalysis A，20122012年发表论文目录1Chengsi Pan, Jing Xu andYongfa Zhu*,Dramatic Activity of C3N4/BiPO4 Photocatalyst with Core-shell Structure formed by Self-assembly，ADVANCED FUNCTIONAL MATERIALS,2012, 22,1518-1524光催化2Yajun Wang, Xiaojuan Bai, Chengsi Pan, Jun He andYongfa Zhu*，Enhancement of Photocatalytic Activity of Bi2WO6 Hybridized with Graphite-Like C3N4，JOURNAL OF MATERIALS CHEMISTRY, 2012,22, 11568-11573光催化3Chengsi Pan, Jing Xu, Yi Chen andYongfa Zhu*,Influence of OH-related Defects on the Performances of BiPO4 Photocatalyst for the Degradation of Rhodamine B,Applied Catalysis B,2012,115, 314-319光催化4Liwu Zhang,Yongfa Zhu*,A review of controllable synthesis and enhancement of performances of bismuth tungstate visible-light-driven photocatalysts,Catalysis Science & Technology,2012,2(4),694-706光催化5Di Li,Yongfa Zhu*,Synthesis of CdMoO4 microspheres by self-assembly and Photocatalytic Performances,CrystEngComm, 2012, 14 (3), 1128 - 1134光催化6WU Xiao-Qin*, ZONG Rui-Long ,ZHU Yong-Fa*,Enhanced MnO2 Nanorods to CO and Volatile Organic Compounds Oxidative Activity by Platinum Nanoparticles,Acta Phys. Chim. Sin., 2012, 28(2)，437-444光催化7LIU Yan-Fang, MA Xin-Guo, YI Xin,ZHU Yong-Fa*.Controllable Synthesis and Photocatalytic Performance of Bismuth Phosphate Nanorods.Acta Phys. Chim. Sin., 2012, 28 (03): 654-660光催化2011年发表论文目录1Yajun Wang, Rui Shi, Jie Lin and Yongfa Zhu*,Enhancement of photocurrent and photocatalytic activity of ZnO hybridized with graphite-like C(3)N(4),ENERGY & ENVIRONMENTAL SCIENCE,2011,4(8),2922-2929光催化2Xinguo Ma, Ying Wu,Yanhui Lu, Jing Xu, Yajun Wang,Yongfa Zhu*,Effect of Compensated Codoping on the Photoelectrochemical Properties of Anatase TiO2 Photocatalyst,The Journal of Physical Chemistry,2011,115(34):16963-16969光催化3Xinguo Ma, Bin Lu, Di Li, Rui Shi, Chenshi Pan, and Yongfa Zhu*,Origin of Photocatalytic Activation of Silver Orthophosphate from First-Principles,JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(11):4680-4687光催化4Tongguang Xu, Liwu Zhang, Hanyun Cheng,Yongfa Zhu*，Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study，Applied Catalysis B: Environmental，101 (2011) 382–387光催化5Rui Shi, Yajun Wang, Feng Zhou and Yongfa Zhu*,Zn3V2O7(OH)(2)(H2O)(2) and Zn3V2O8 nanostructures: controlled fabrication and photocatalytic performance,JOURNAL OF MATERIALS CHEMISTRY,2011,21(17):6313-6320光催化6Chengsi Pan andYongfa Zhu*,Size-controlled synthesis of BiPO4 nanocrystals for enhanced photocatalytic performance,Journal of Materials Chemistry,2011, 21, 4235–4241光催化7Zhang Liwu; Man Yi; Zhu Yongfa*,Effects of Mo Replacement on the Structure and 2 Visible-light-induced Photocatalytic Performances of Bi2WO6 Photocatalyst,ACS Catalysis,2011,1(8),841-848光催化8Chengsi Pan, Di Li, Xinguo Ma, Yi Chenand Yongfa Zhu*,Effects of Distortion of PO4 Tetrahedron on the Photocatalytic Performances of BiPO4,Catalysis Science & Technology,2011,1(8):1399-1405DOI:10.1039/c1cy00261a光催化9Di Li, Rui Shi, Chengsi Pan and Yongfa Zhu*,Influence of ZnWO4 nanorod aspect ratio on the photocatalytic activity,CRYSTENGCOMM, 2011,13(14):4695-4700光催化10Di Li, Chengsi Pan, Rui Shi, Yongfa Zhu*,Controllable synthesis of Fe5(PO4)4(OH)3·2H2O as a highly efficient heterogeneous Fenton-like catalysts,CrystEngComm., 2011,13(22):6688-6693DOI:10.1039/c1ce05483j光催化11Yajun Wang, JieLin, Rui Shi Yongfa Zhu*,Enhanced Photoelectric Catalytic Degradation of Methylene Blue via TiO2 Nanotube Arrays Hybridized with Graphite-like Carbon,Journal of Molecular Catalysis A: Chemical,349 (2011) 13– 19光催化12Huang Guangli, Shi Rui, Zhu Yongfa*,Photocatalytic Activity and Photoelectric Performance Enhancement for ZnWO4 by Fluorine Substitution,Journal of Molecular Catalysis. A, Chemical348 (2011), pp. 100-105光催化13Yajun Wang,JingXu,WeizhengZong,YongfaZhu ,Enhancement of photoelectric catalytic activity of TiO2 film via Polyaniline hybridization，JOURNAL OF SOLID STATE CHEMISTRY,2011,184(6),1433-1438光催化14Feng Zhou, Rui Shi, Yongfa Zhu,Significant Enhancement of the Visible Photocatalytic Degradation Performances of Bi2MoO6 Nanoplate by Graphene Hybridization,Journal of Molecular Catalysis A: Chemical,2011,340,77-82光催化15Yao Wen-qing, Zong Rui-long,Zhu Yong-fa*, Standard Sample Preparation Method for Quick Determination of Trace Elements in Plastic,SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011,31(8): 2274-2277环境分析2010年发表论文目录1Haipeng Yang*,Yongfa Zhu, Dongcheng Chen, Chunhui Li, Shiguo Chen, Zaochuan Ge，Electrochemical biosensing platforms using poly-cyclodextrin and carbon nanotube composite，Biosensors and Bioelectronics26 (2010) 295–298分析化学2Yajun Wang, Rui Shi, Jie Lin, andYongfa Zhu*，Significant photocatalytic enhancement of TiO2photocatalysts via graphene-like carbon in-situ hybridization，Applied Catalysis B: Environmental，100 (2010) 179–183光催化3Rui Shi; Yajun Wang; Di Li; Jing Xu;Yongfa Zhu*，Synthesis of ZnWO4 Nanorods with [100] Orientation and Enhanced Photocatalytic Properties，Applied Catalysis B: Environmental，100 (2010) 173–178光催化4Liwu Zhang, Yajun Wang, Tongguang Xu, Shengbao Zhu,Yongfa Zhu*，Surface hybridization effect of C60 molecules on TiO2 and enhancement of the photocatalytic activity，Journal of Molecular Catalysis A: Chemical2010，331 7–14光催化5Chengsi Pan，Yongfa Zhu*，New Type of BiPO4 Oxy-Acid Salt Photocatalyst with High Photocatalytic Activity on Degradation of Dye，Environ.Sci.Technol.2010,44,5570–5574光催化6Liwu Zhang, Tongguang Xu, Xu Zhao,Yongfa Zhu*，Controllable synthesis of Bi2MoO6 and effect of morphology and variation in local structure on photocatalytic activities，Applied Catalysis B: Environmental98 (2010) 138-146光催化7Hao Zhang andYongfa Zhu*，Significant Visible Photoactivity and Antiphotocorrosion Performance of CdS Photocatalysts after Monolayer Polyaniline Hybridization，J. Phys. Chem. C2010,114,5822–5826光催化8Rui Shi, Jie Lin, Yajun Wang, Jing Xu, andYongfa Zhu*，Visible-Light Photocatalytic Degradation of BiTaO4 Photocatalyst and Mechanism of Photocorrosion Suppression，J. Phys. Chem. C2010,114,6472–6477光催化9Shuhui Liang, Tongguang Xu, Fei Teng, Ruilong Zong,Yongfa Zhu *，The high activity and stability of La0.5Ba0.5MnO3 nanocubes in the oxidation of CO and CH4，Applied Catalysis B: Environmental96 (2010) 267–275环境催化10ZONG WeiZheng，ZHU YongFa*，Preparation of Single Chamber Solid Oxide Fuel Cell by Co-Pressing and Direct Forming Process,Acta Phys.Chim. Sin.,2010, 26(4)：827-832能源化学11WWu Xiao-Qin, Zong Rui-Long,Mu Hao-Jie,Zhu Yong-Fa*，Cataluminescence Performance on Catalysts of Graphene Supported Platinum，ACTA PHYSICO-CHIMICA SINICA，2010，26(11),3002-3008分析化学2009年发表论文目录1Liwu Zhang, Yajun Wang, Hanyun Cheng, Wenqing Yao, andYongfa Zhu*，Synthesis of Bi2WO6Porous Thin Films as Efficient Visible-Active Photocatalyst，Adv. Mater.,2009,21,12,1286-1290光催化2Zhang H, Zong RL,Zhu YF*，Photocorrosion Inhibition and Photoactivity Enhancement for Zinc Oxide via Hybridization with Monolayer Polyaniline,J. Phys. Chem. C，2009,113, 4605–4611光催化3Liwu Zhang, Hanyun Cheng, Ruilong Zong,Yongfa Zhu*,Photocorrosion suppression of ZnO nanoparticles via hybridization with graphite-like carbon and enhanced photocatalytic activity,J. Phys. Chem. C，2009,113,2368–2374光催化4Fei Teng*, Wenqing Yao,Yongfa Zhu*, Mindong Chen, Ranhui Wang, Sun-il Mho, and Dennis Desheng Meng，Correlation Cataluminescence (CTL) Property with Reactivity of Hydrothermally Synthesized La0.8Sr0.2MnO3 Cubes and CTL as a Rapid Mode of Screening Catalyst，J. Phys. Chem. C, 2009, 113 (8), 3089-3095环境催化5Rui Shi, Guangli Huang, Jie Lin, andYongfa, Zhu*，Photocatalytic Activity Enhancing for Bi2WO6by Fluorine Substitution，J. Phys. Chem. C，2009,113 , 19633-19638光催化6JIE LIN, RUILONG ZONG, MI ZHOU,YONGFA ZHU*,Photoelectric Catalytic Degradation of Methylene Blue by C60-Modified TiO2Nanotube Array,Applied Catalysis B, Environmental, 2009, 89(3-4),425-431光催化7Xu Zhao, Tongguang Xu, Wenqing YaoaandYongfa Zhu*,Synthesis and photoelectrochemical properties of thin bismuth molybdates film with various crystal phases,THIN SOLID FILMS,2009, 517(20),5813-5818光催化8Xu Zhao, Tongguang Xu, Wenqing YaoaandYongfa Zhu*,Photodegradation of dye pollutants catalyzed by gamma-Bi2MoO6 nanoplate under visible light irradiation,APPLIED SURFACE SCIENCE,2009,255(18),8036-8040光催化9Fuxin Zhong, Ruilong Zong andYongfa Zhu*,Platinum nanowire array electrochemical sensor: Fabrication and Characterization, Journal Nanoscience and Nanotechnology,2009, 9(4),2437-2441.分析2008年发表论文目录1Liwu Zhang, Hongbo Fu,Yongfa Zhu*,An Efficient TiO2Photocatalyst by Surface Hybridization with Graphite-like Carbon,Adv. Funct. Mater.,2008, 18, 2180–2189光催化2Guangli Huang†, Shicheng Zhang‡, Tongguang Xu†,Yongfa Zhu*†,Fluorination of ZnWO4Photocatalyst and Influence on the Degradation Mechanism for 4-Chlorophenol,Environ.Sci.Technol.2008, 42 (22), 8516-8521.光催化3Hongbo Fu†‡, Tongguang Xu†, Shengbao Zhu†, andYongfa Zhu†,*,Photocorrosion Inhibition and Enhancement of Photocatalytic Activity for ZnO via Hybridization with C60,Environ.Sci.Technol.2008, 42 (21), 8064-8069.光催化4Fei Teng*, Tongguang Xu , Yang Teng , Shuhui Liang , Bulgengauge, Jie Lin, Wenqing Yao , Ruilong Zong ,Yongfa Zhu *,andYoufei Zheng,A CL Mode Detector for Rapid Catalyst Selection and Environmental Detection Fabricated by Perovskite Nanoparticles,Environ.Sci.Technol.2008, 42, 3886–3892光催化5Hongbu Fu, Shicheng Zhang, Tongguang Xu,Yongfa Zhu*, and Jiaming Chen*,Photocatalytic Degradation of RhB by Fluorinated Bi2WO6 and Distributions of the Intermediate Products,Environ.Sci.Technol.2008,42,2085–2091光催化6Hao Zhang, Ruilong Zong, Jincai Zhao, andYongfa Zhu*,Dramatic Visible Photocatalytic Degradation Performances Due to Synergetic Effect of TiO2 with PANI,Environ.Sci.Technol.2008,42,3803–3807光催化7Liwu Zhang, Hongbo Fu, Chuan Zhang, andYongfa Zhu*，Effects of Ta5+Substitution on the Structure and Photocatalytic Behavior of the Ca2Nb2O7Photocatalyst，J. Phys.Chem.C.;2008;112(8); 3126-3133光催化8Shuhui Liang, Fei Teng, G.Bulgan, Ruilong Zong andYongfa Zhu*,Effect of Phase Structure of MnO2 Nanorod Catalyst on the Activity for CO Oxidation,J.Phys. Chem.C2008, 112, 5307-5315环境催化9Fei Teng, Yi Man, Shuhui Liang, Buergen Gaugue,Yongfa Zhu*, Wei Han, Zheming Wang, Ping Xu,Guoxing Xiong, Zhijian Tian，Effect of the morphology on thermal stability of the Ba-Ce-Mn-Al-O oxides synthesized in a reverse microemulsion，Journal of Alloys and Compounds461 (2008) 516–520环境催化10Fei Teng, Wei Qu, Guodong Wen, Zheming Wang, Zhijian Tian, Xiaomei Yang, Ping Xu,Yongfa Zhu*, Guoxing Xiong,Effect of the flowing gases of steam and CO2 on the texture and catalytic activity for methane combustion of MgO powders,Microporous and Mesoporous Materials111 (2008) 620–626环境催化11Fei Teng, Tongguang Xu, Shuhui Liang, Gauloo Buergen, Wenqing Yao,Yongfa Zhu*,Synthesis of hollow Mn3O4-in-Co3O4magnetic microspheres and its chemiluminescence and catalytic properties,Catalysis Communications,Volume 9, Issue 6,31 March 2008,Pages 1119-1124环境催化12FEI TENG, Li Wang,Yongfa Zhu*;Controllable hiberarchy Nanostructures with Mesopores by a Facile “Framework-Template in situ” Process;Colloid and Surface A.312 (2008) 39–46环境催化13Hongbo Fu, Shicheng Zhang, Liwu Zhang,Yongfa Zhu*，Visible–light–driven NaTaO3−xNxcatalyst prepared by a hydrothermal process.Mater. Res. Bull.Materials Research Bulletin 43 (2008) 864–872光催化14Shengbao Zhu, Hongbo Fu, Shicheng Zhang, Liwu Zhang,Yongfa Zhu*.Two-step synthesis of a novel visible-light (≤ 600 nm)–driven NaTaO3-xNxcatalyst for the pollutants decomposition.J. Photochem. Photobio. A，2008, 193: 33–41光催化15Xu Zhao.,Zongwei Li., Yi Chen.,Yongfa Zhu*,Enhancement of photocatalytic degradation of polyethylene plastic with CuPc modified TiO2photocatalyst under solar light irradiation.Applied Surface Science，254 (2008) 1825–1829光催化16Fei Teng, Tongguang Xu, Youfei Zheng, Shuhui Liang, Bulgen Gochoo, Xiaohua Gu, Ruilong Zong, Wenqing Yao,Yongfa Zhu*,Formation of hollow NiO single crystals and Ag/NiO flowers,Materials Research Bulletin, 43(2008)3562-3569环境催化17Hongbo Fu, Wenqing Yao,Yongfa Zhu*.The enhanced photoactivity of nanosized Bi2WO6for the photodegradation of 4–CP.Mater. Res. Bull.43(2008) 2617-2625光催化18Fei Teng, Wenqing Yao, Youfei Zheng, Yutao Ma, Yang Teng, Tongguang Xu, Shuhui Liang,YongfaZhu*,Synthesis of flower-like CuO nanostructures as a sensitive sensor for catalysis,Sensors and Actuators B: Chemical,Volume 134, Issue 2,25 September 2008,Pages 761-768环境催化19Fei Teng, Wenqing Yao, Youfei Zheng, Yutao Ma, Tongguang Xu, Guizhi Gao, Shuhui Liang, Yang Teng,Yongfa Zhu*,Facile synthesis of hollow Co3O4microspheres and its use as a rapid responsive CL sensor of combustible gases,Talanta,Volume 76, Issue 5,15 September 2008,Pages 1058-1064环境催化20Fei Teng*,Wenqing Yao, Youfei Zheng, Yutao Ma, Tongguang Xu, Guizhi Gao,Shuhui Liang, Yang Teng,Yongfa Zhu*,Facile synthesis of hollow Co3O4 microspheres and its use as a rapid responsive CL sensor of combustible gases,Talanta, 76 (2008) 1058–1064环境催化21BULGAN G.,ZONG Rui Long, LIANG Shu Hui, YAO Wen Qing,ZHU Yong Fa*,CO Cataluminescence Property of Platinum Supported Composite Oxide Catalysts,Acta Phys. Chim. Sin., 2008, 24(9)：1547-September 1552环境催化22BULGAN G.,LIANG Shu Hui, TENG Fei, YAO Wen Qing,ZHU Yong Fa*,Effect of Ce Doping on the Structure and Catalytic Activity of La1-xCexCoO3 Catalysts,Acta Phys. Chim. Sin., 2008, 24(2)：205-February 210环境催化23ZHOU Jun，WU Ke SUN，Yue CONG，JianBo WANG，ChangZhen CHANG，Xiang XIAN，Hong,ZHU，YongFa*,A Novel Method for Quantitative Analysis of Total Particulate phase Free Radicals in Mainstream Cigarette Smoke,ACTA CHIMICA SINICA, Vo1．66，2008, No．2，216~ 222分析2007年发表论文目录1Liwu Zhang, Li Wang, Yongfa Zhu*,Synthesis and Performance of BaAl2O4 with a Wide Spectral Range of Optical Absorption.,Adv. Funct. Mater. 2007,18 3781光催化2Zhu, S.; Xu, T.; Fu, H.; Zhao, J.; Zhu, Y.,Synergetic Effect of Bi2WO6Photocatalyst with C60and Enhanced Photoactivity under Visible Irradiation,Environ. Sci. Technol.2007, 41, 6234-6239光催化3Huang, G.; Zhu, Y.,Enhanced Photocatalytic Activity of ZnWO4Catalyst via Fluorine Doping,J. Phys. Chem. C.;(Article); 2007;111(32); 11952-11958.光催化4Xu Zhao Tongguang Xu Wenqing Yao Chuan ZhangYongfa Zhu*,Photoelectrocatalytic degradation of 4-Chlorophenol at Bi2WO6 nanoflake film electrode under visible light irradiation,Applied Catalysis B, Environmental, 72 (2007) 92–97光催化5IJie Lin, Jun Lin, and Yongfa Zhu*,Controlled Synthesis of the ZnWO4 Nanostructure and Effects on the Photocatalytic Performance, Inorg. Chem. 2007, 46, 8372-8378;光催化6Fei Teng, Wei Han, Shuhui Liang, Buergen Gaugeu, Ruilong Zong andYongfaZhu*,Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3single-crystal cubes in the oxidation of CO and CH4,Journal of Catalysis,Volume 250, Issue 1,15 August 2007,Pages 1-11环境催化7Teng, F.; Liang, S.; Gauge, B.; Zhu, Y.; Xu, J.; Wen, G.; Tian, Z.; Wang, Z.; Yang, X.; Xiong, G., Syntheses of La1-xBaxMn2Al10O19Catalysts (x= 0, 0.05) in a Novel Microemulsion of Water/2-Propanol/1-Butanol and Their High Activities in Methane Combustion,J. Phys. Chem. C.;(Article); 2007;111(29); 10941-10947.环境催化8Shuhui Liang, Fei Teng, G. Bulgan, andYongfa Zhu*,Effect of Jahn-Teller Distortion in La0.5Sr0.5MnO3Cubes and Nanoparticles on the Catalytic Oxidation of CO and CH4.,J. Phys. Chem. C2007, 111, 16742环境催化9Haipeng Yang andYongfaZhu*,Glucose biosensor based on nano-SiO2and “unprotected” Pt nanoclusters,Biosensors and Bioelectronics,Volume 22, Issue 12,15 June 2007,Pages 2989-2993纳米分析10Jun Zhou, Ruoshi Bai andYongfa Zhu*，Determination of four tobacco-specific nitrosamines in mainstream cigarette smoke by gas chromatography/ion trap mass spectrometry，Rapid Commun. Mass Spectrom.2007; 21: 4086–4092分析11Guangli Huang, Chuan Zhang,Yongfa Zhu*,ZnWO4 photocatalyst with high activity for degradation of organic contaminants,Journal of Alloys and Compounds432 (2007) 269–276光催化12Xu Zhao, Yan Wu, Wenqing Yao,Yongfa Zhu*,Photoelectrochemical properties of thin Bi2WO6 films,Thin Solid Films515 (2007) 4753–4757光催化13Hongbo Fu, Chengsi Pan, Liwu Zhang,Yongfa Zhu*,Synthesis, characterization and photocatalytic properties of nanosized Bi2WO6, PbWO4 and ZnWO4 catalysts,Materials Research Bulletin42 (2007) 696–706光催化14Zhang Shicheng*, Yao Wenqing,Zhu Yongfa*, Shi Liyi,Preparation and Photoelectrochemical Preoperties of Bi2WO6 Filmswith Visible Light Response,Acta Physico-Chimica Sinica, 23(1)：111-115，2007光催化15Fei Teng, Bulgen Gaugeu, Shuhui Liang andYongfaZhu*,Preparation of LaSrCuO4nanowires by carbon nanotubes and their catalytic and chemiluminescence properties for CO oxidation,Applied Catalysis A: General,Volume 328, Issue 2,10 September 2007,Pages 156-162环境催化16Fei Teng, Yi Man, Buergen Gaugeu, Ruilong Zong, Wenqing Yao,Yongfa Zhu*,Crystal Structure Stability and Catalytic Activity of Magnetoplumbite (MP) Catalyst doped with Mn and Mg.,Journal of Non-Crystalline Solids2007, 353, 4806环境催化17Xu Zhao, Manhong Liu andYongfaZhu*,Fabrication of porous TiO2film via hydrothermal method and its photocatalytic performances,Thin Solid Films,Volume 515, Issue 18,25 June 2007,Pages 7127-7134光催化18Guangli Huang andYongfaZhu*,Synthesis and photocatalytic performance of ZnWO4catalyst,Materials Science and Engineering: B,Volume 139, Issues 2-3,15 May 2007,Pages 201-208;光催化19Yan Wu, Wenqing Yao andYongfaZhu*,Interfacial Structure of Ta2O5/Si Film and Photoactivity,Acta Physico-Chimica Sinica,Volume 23, Issue 5,May 2007,Pages 625-629光催化20Xu Zhao, Zongwei Li, Yi Chen, Liyi Shi andYongfaZhu*,Solid-phase photocatalytic degradation of polyethylene plastic under UV and solar light irradiation,Journal of Molecular Catalysis A: Chemical,Volume 268, Issues 1-2,1 May 2007,Pages 101-106光催化21F. Teng, S. Liang, B. Gaugeu, R. Zong, W. Yao,Y. Zhu*,Carbon Nanotubes-Templated Assembly of LaCoO3 Nanowires at Low Temperatures and Its Excellent Catalytic Properties for CO oxidation,Catalysis Communications8 (2007) 1748–1754环境催化22Bulgan.G,Teng Fei, Liang shuhui,Yao Wenqing,Zhu Yongfa*,Effect of Cu Doping on the Structure and Catalytic Activity of LaMnO3 Catalyst,Acta Physico-Chimica Sinica,2007, 23(9), 1387环境催化23Yi Man, Ruilong Zong,Yongfa Zhu*，Preparation and Photoelectrochemical Properties of Bi2MoO6 Films., Acta Phys. -Chim. Sin., 2007, 23(11): 1671-1676.光催化24Wu Y, Zhang SC, Zhang LW,Zhu YF*,Photocatalytic activity of nanosized ZnWO4prepared by the sol-gel method.,CHEMICAL RESEARCH IN CHINESE UNIVERSITIES2007, 23 (4), 465光催化25ZHOU Jun , WU Ke , SUN Yue , CONG J ian Bo , WANG ChangZhen ,CHANG Xiang , XIAN Hong ,ZHU YongFa*，Development of a Quantitative Method for Analyzing Gas phase Free Radicals in Mainstream Cigarette Smoke，CHEM ICAL JOURNAL OF CH INESE UN IVERSITIES，2007, 28 (10), 1846分析2006年发表论文目录1Xu TG, Zhang C, Shao X, Wu K,Zhu YF*.Monomolecular-layer Ba5Ta4O15 nanosheets: Synthesis and investigation of photocatalytic properties,ADVANCED FUNCTIONAL MATERIALS16 (12): 1599-1607 AUG 4 2006光催化2Zhao X,Zhu YF*,Synergetic degradation of rhodamine B at a porous ZnWO4 film electrode by combined electro-oxidation and photocatalysis,ENVIRONMENTAL SCIENCE & TECHNOLOGY40 (10): 3367-3372 MAY 15 2006光催化3Fu HB, Zhang LW, Zhang SC,Zhu YF*, Zhao JC,Electron spin resonance spin-trapping detection of radical intermediates in N-doped TiO2-assisted photodegradation of 4-chlorophenol,JOURNAL OF PHYSICAL CHEMISTRY B110 (7): 3061-3065 FEB 23 2006光催化4Xu Tongguang, Zhao Xu,Zhu Yongfa*,Synthesis of Hexagonal BaTa2O6 Nanorods and Influence of Defects on the Photocatalytic Activity,Journal of Physical Chemistry B,110,25825-25832,2006光催化5Fu HB, Zhang LW, Yao WQ,Zhu YF*,Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process,APPLIED CATALYSIS B-ENVIRONMENTAL66 (1-2): 100-110 JUN 20 2006光催化6Fu HB, Lin J, Zhang LW,Zhu YF*,Photocatalytic activities of a novel ZnWO4 catalyst prepared by a hydrothermal process,APPLIED CATALYSIS A-GENERAL306: 58-67 JUN 7 2006光催化7Zhao X, Yao WQ, Wu Y, Zhang SC, Yang HP,Zhu YF*,Fabrication and photoelectrochemical properties of porous ZnWO4 film,JOURNAL OF SOLID STATE CHEMISTRY179 (8): 2562-2570 AUG 2006光催化8Zhang LW, Fu HB, Zhang C,Zhu YF*,Synthesis, characterization, and photocatalytic properties of InVO4 nanoparticles,JOURNAL OF SOLID STATE CHEMISTRY179 (3): 804-811 MAR 2006光催化9Zhang SC, Zhang C, Yang HP,Zhu YF*,Formation and performances of porous InVO4 films,JOURNAL OF SOLID STATE CHEMISTRY179 (3): 873-882 MAR 2006光催化10Zhang SC, Zhang CA, Man Y,Zhu YF*,Visible-light-driven photocatalyst of Bi2WO6 nanoparticles prepared via amorphous complex precursor and photocatalytic properties,JOURNAL OF SOLID STATE CHEMISTRY179 (1): 62-69 JAN 2006光催化11Yao WQ, Yang HP, Chang Y,Zhu YF*,Preparation and conducting performance of LaNiO3/Ag film and its interface reaction,APPLIED SURFACE SCIENCE252 (20): 7461-7468 AUG 15 2006薄膜材料12Yang HP,Zhu YF*,Size dependence of SiO2 particles enhanced glucose biosensor,TALANTA68 (3): 569-574 JAN 15 2006纳米分析2005年发表论文目录1Zhang C,Zhu YF*,Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts，CHEMISTRY OF MATERIALS17 (13): 3537-3545 JUN 28 2005光催化2Fu HB, Pan CS, Yao WQ,Zhu YF*,Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6,JOURNAL OF PHYSICAL CHEMISTRY B109 (47): 22432-22439 DEC 1 2005光催化3Li Wang andYongfaZhu*，Effectsof Nanostructure on Catalytic Degradation of Ethanol on SrCO3 Catalysts，J. Phys. Chem. B2005,109,5118-5123环境催化4Ruiqin Tan,Yongfa Zhu*，Poisoning mechanism of perovskite LaCoO3 catalyst by organophosphorous gas，Applied Catalysis B: Environmental58 (2005) 61–68环境催化5Yongfa Zhu*, Fang Yu, Yi Man, Qingyong Tian, Yu He, Nianzu Wu，Preparation and performances of nanosized Ta2O5 powder photocatalyst，Journal of Solid State Chemistry178 (2005) 224–229光催化6Yongfa Zhu*, Hai Wang, Peng Liu, Wenqing Yao, Lili Cao，Preparation and conducting performance of LaNiO3 thin film on Si substrate，Thin Solid Films471 (2005) 48– 52材料与表面7Yang HP,Zhu YF*，A high performance glucose biosensor enhanced via nanosized SiO2，ANALYTICA CHIMICA ACTA554 (1-2): 92-97 DEC 4 2005分析化学8L. Lin , W. Lin, Y.X. Zhu,B.Y. Zhao, Y.C. Xie, Y. He,Y.F. Zhu，Uniform carbon-covered titania and its photocatalytic property，Journal of Molecular Catalysis A: Chemical236 (2005) 46–53合作，催化9Zhang JP, Sun ZM, Shi LY*,Zhu YF，Preparation of TiO2 film on stainless steel webnet and the degradation of formaldehyde，JOURNAL OF INORGANIC MATERIALS20 (5): 1243-1249 SEP 2005